Catalysts for Fine Chemical Synthesis. Regio- and Stereo- by Stanley M. Roberts, John Whittall

By Stanley M. Roberts, John Whittall

Quantity five within the Catalysts for positive Chemical Synthesis sequence describes new techniques for the regio- and stereo-controlled modifications of compounds related to oxidation or aid reactions. It describes quite a lot of catalysts, together with organometallic platforms, biocatalysts and biomimetics. This quantity additionally comprises descriptions of a number of conversions, together with: Baeyer-Villiger oxidations; Epoxidation reactions; Hydroxylation reactions; Oxidation of alcohols to aldehydes, ketones and carboxylic acids; aid of ketones; and relief of alkenes together with α, β-unsaturated carbonyl compounds. The ebook might be a big textual content for training artificial natural chemists in and academia.

  • Protocols are written in a customary structure through the authors who've chanced on them
  • Hints, guidance and security suggestion (where applicable) is given to make sure that the strategies are reproducible
  • Indications are given as to the diversity of beginning fabrics used and, the place applicable, comparisons to substitute methodology
  • Includes proper references to the first literature.

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Extra info for Catalysts for Fine Chemical Synthesis. Regio- and Stereo- Controlled Oxidation and Reductions

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CONCLUSION . . . . . . . . . . . . . . . . . . . . . . . . . REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . 2 SYNTHESIS AND APPLICATION OF PHOSPHINITE OXAZOLINE IRIDIUM COMPLEXES FOR THE ASYMMETRIC HYDROGENATION OF ALKENES . . . . . . . 1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4, 5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol . . . . . . . . 2 Synthesis of (4S,5S)-O-[1-Benzyl-1(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]diphenylphosphinite .

2 Synthesis of (4S,5S)-O-[1-Benzyl-1(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]diphenylphosphinite . . . . . . . . . . . . . . . . . . 3 Synthesis of (4S,5S)-[(Z4-1,5-Cyclooctadiene)-{2-(2-phenyl-5methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinitepropane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate . . 4 Asymmetric hydrogenation of trans-a-Methylstilbene . . . . . . CONCLUSION . . . . . . . . . . . . . . . . . .

And Knochel, P. Enantioselective Preparation of C2-Symmetrical Ferrocenyl Ligands for Asymmetric Catalysis. Chem. Eur. J. 1998, 4, 950–968. 47. -E. and Rosling, A. Highly Catalytic Enantioselective Reduction of Aromatic Ketones using Chiral Polymer-supported Corey, Bakshi, and Shibata Catalysts. Tetrahedron Asymmetry 2004, 15, 1495–1499. 48. , Liu, D. and Sun N. Asymmetric Reduction of Oxime Ethers Promoted by Chiral Spiroborate Esters with an O3BN Framework. J. Org. Chem. 2006, 71, 3998– 4001.

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